Sodium tri-sec-butyL
N-selectride
CAS: 67276-04-4
Molecular Formula: C12H28BNa
Sodium tri-sec-butyL - Names and Identifiers
| Name | N-selectride |
| Synonyms | N-selectride n-selectride Sodium tri-sec-butyL Sodium tri(s-butyl)borohydride SODIUM TRI-SEC-BUTYLBOROHYDRIDE sodiuM tri-sec-butylhydroborate sodium tri-sec-butylborohydride solution sodiumtri-sec-butylborohydride,calselect?na, Borate(1-), hydrotris(1-methylpropyl)-, sodium, (T-4)- sodiumtri-sec-butylborohydride,calselect?na,intetrahydrofuran |
| CAS | 67276-04-4 |
| EINECS | 266-630-5 |
| InChI | InChI=1/C12H27B.Na/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-12H,7-9H2,1-6H3;/q-1;+1 |
Sodium tri-sec-butyL - Physico-chemical Properties
| Molecular Formula | C12H28BNa |
| Molar Mass | 206.15 |
| Density | 0.893g/mLat 25°C(lit.) |
| Flash Point | 5°F |
| Storage Condition | Flammables + water-Freezer (-20°C)e area |
Sodium tri-sec-butyL - Risk and Safety
| Risk Codes | R11 - Highly Flammable R14/15 - R19 - May form explosive peroxides R22 - Harmful if swallowed R34 - Causes burns R37 - Irritating to the respiratory system R40 - Limited evidence of a carcinogenic effect |
| Safety Description | S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S27 - Take off immediately all contaminated clothing. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) |
| UN IDs | UN 3399 4.3/PG 1 |
| WGK Germany | 1 |
| HS Code | 29319090 |
Sodium tri-sec-butyL - Introduction
N-selectride(N-selectride) is a commonly used strong reducing agent. The following is a description of the nature, use, preparation and safety information of the N-selectride:
Nature:
1. Appearance: colorless or light yellow solid.
2. molecular formula: C12H27BNa.
3. Molecular weight: 208.24g/mol.
4. Solubility: Soluble in hydrocarbons and non-polar solvents, insoluble in water.
Use:
1. Reducing agent: N-selectride can be used as a strong reducing agent for selective reduction of ketones, aldehydes and other functional groups.
2. Reaction catalyst: It can be used as a catalyst in organic synthesis to promote various hydrogenation reactions, including enantioselective reduction.
3. electron donor: N-selectride can be used as an electron donor in organometallic chemical reactions.
Preparation Method:
There are many methods for the preparation of N-selectride, but the most commonly used is through the reaction of tri-sec-butyl aluminum borohydride with sodium chloride. The specific preparation process may be carried out under an inert atmosphere.
Safety Information:
1. the N-selectride has strong reducibility, and the old version of basketball live app should be operated in a well-ventilated environment.
2. Observe strict safety measures when preparing and using N-selectride, including wearing protective gloves, glasses and protective clothing.
3. avoid contact with water to prevent the formation of combustible gas due to water decomposition.
4. should be stored away from the fire and oxidant, avoid high temperature and open fire.
5. N-selectride on the skin and eyes with irritation, such as accidental contact, should immediately rinse with plenty of water, and medical treatment.
Please note that this information is for reference only, and specific operation and use should be carried out according to specific experimental conditions and safe operating procedures.
Nature:
1. Appearance: colorless or light yellow solid.
2. molecular formula: C12H27BNa.
3. Molecular weight: 208.24g/mol.
4. Solubility: Soluble in hydrocarbons and non-polar solvents, insoluble in water.
Use:
1. Reducing agent: N-selectride can be used as a strong reducing agent for selective reduction of ketones, aldehydes and other functional groups.
2. Reaction catalyst: It can be used as a catalyst in organic synthesis to promote various hydrogenation reactions, including enantioselective reduction.
3. electron donor: N-selectride can be used as an electron donor in organometallic chemical reactions.
Preparation Method:
There are many methods for the preparation of N-selectride, but the most commonly used is through the reaction of tri-sec-butyl aluminum borohydride with sodium chloride. The specific preparation process may be carried out under an inert atmosphere.
Safety Information:
1. the N-selectride has strong reducibility, and the old version of basketball live app should be operated in a well-ventilated environment.
2. Observe strict safety measures when preparing and using N-selectride, including wearing protective gloves, glasses and protective clothing.
3. avoid contact with water to prevent the formation of combustible gas due to water decomposition.
4. should be stored away from the fire and oxidant, avoid high temperature and open fire.
5. N-selectride on the skin and eyes with irritation, such as accidental contact, should immediately rinse with plenty of water, and medical treatment.
Please note that this information is for reference only, and specific operation and use should be carried out according to specific experimental conditions and safe operating procedures.
Last Update：2024-04-10 22:29:15
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Email: r@reformchem.com
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Product Name: Sodium tri-sec-butylborohydride Request for quotationCAS: 67276-04-4
Tel: 15001012717
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